Product ID:COMPOUND 71-312, PART B
MSDS Date:01/01/1987
FSC:8040
NIIN:00F003897
MSDS Number: BBPBC

MAGNOLIA PLASTICS INC

5547 PEACHTREE INDUSTRIAL BLVD
CHAMBLEE, GA 30341-2234
US

Emergency Phone: (404) 451-2777

Cage: 22121

MAGNOLIA PLASTICS INC

CHAMBLEE, GA 30341-2234 US

Telephone: (770) 451-2777/(800) 457-4280

Cage: 22121

4,4'-METHYLENE DIANILINE (SARA III)

CAS: 101-77-9

RTECS: BY5425000

Fraction By Weight: 25%

ACGIH TLV: S; 0.1 PPM; A2; 9192

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

LD50 LC50 Mixture:NOT GIVEN
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:TOXIC BY INHALATION AND SKIN CONTACT.
SUSPECTED HUMAN CARCINOGEN. MAY CAUSE EYE IRRITATION, SKIN
IRRITATION, RESPIRATORY TRACT IRRITATION.
Explanation of Carcinogenicity:PRODUCT CONTAINS MDA (101-77-9) WHICH IS
LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN.
Effects of Overexposure:FEVER, CHILLS, ANOREXIA, VOMITING. MAY CAUSE
TRANSIENT LIVER DAMAGE AND CYANOSIS, EYE IRRITATION, SKIN
IRRITATION, RASHES, RESPIRATORY TRACT IRRITATION.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:SKIN: REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP & WATER.
LAUNDER CLOTHING PRIOR TO RE-USE. EYES: FLUSH WITH WATER FOR 15
MINUTES. GET MEDICAL ATTENTION. INHALATION: REMOVE VICTIM TO FRESH
AIR. ADMI NISTER OXYGEN. INGESTION: INDUCE VOMITING. GIVE WATER.

Flash Point Method:PMCC
Flash Point:>200F,>93C
Extinguishing Media:WATER SPRAY, FOAM, CO2, DRY CHEMICAL
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA &
FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER
SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.

Spill Release Procedures:REMOVE SPILLAGE BY ABSORBING IN SAND OR
ABSORBENT SWEEPING COMPOUND, DISPOSE IF IN CSED CONTAINER. FLUSH
CONTAMINATED AREA WITH WATER; COLLECT WATER FOR PROR DISPOSAL.
AVOID CONTACT. CLEANUP PERSONNEL MUST WEAR PROPER PROTECTIVE
EQUIPMENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN A COOL, DRY AREA IN TIGHTLY
CLOSED CONTAINERS. AVOID CONTACT W/SKIN & EYES. USE WITH EQUATE
VENTILATION. USE GOOD HYGIENE PRACTICES.
Other Precautions:DANGER CANCER SUSPECT AGENT. PROLONGED OR REPEATED
CONTACT OF LIQUID OR BREATHING OF VAPORS OR DUSTS MAY CAUSE DELAYED
OR SERIOUS INJURY.

Respiratory Protection:NIOSH APPROVED RESPIRATOR FOR ORGANIC VAPORS.
MAINTAIN BELOW TLV.
Ventilation:LOCAL EXHAUST AND MECHANICAL
Protective Gloves:RUBBER
Eye Protection:GOGGLES
Other Protective Equipment:APPROPRIATE CLOTHING (APRONS, COVERRALLS,
GLOVES, FACE SHIELDS, GOGGLES, ETC) TO PREVENT DERMAL EXPOSURE.
Work Hygienic Practices:WASH WITH SOAP AND WATER AFTER HANDLING PRODUCT
AND BEFORE EATING DRINKING OR SMOKING.
Supplemental Safety and Health
MSDS UPDATED BY DGSC-SSH TO REFLECT OSHA'S MORE STRINGENT STANDARDS FOR
MDA. USER SHOULD CONSULT LOCAL SAFETY OFFICE FOR SPECIFIC DETAILS
OF WORK PRACTICES, MEDICAL SURVEILLANCE AND HOUSEKEEPING PROCE
DURES FOR MDA EXPOSURES.

HCC:T7
Boiling Pt:B.P. Text:>225F,>107C
Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN
Vapor Pres:NIL
Vapor Density:>1
Spec Gravity:2.50
Evaporation Rate & Reference:(BU AC = 1) <1
Solubility in Water:NEGLIGIBLE
Appearance and Odor:BROWN LIQUID
Percent Volatiles by Volume:0%

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRON ACIDS AND BASES
Stability Condition to Avoid:ELEVATED TEMPERATURES
Hazardous Decomposition Products:OXIDES OF CARBON AND NITROGEN
Conditions to Avoid Polymerization:LARGE MIXTURES IN BULK. CURING
PROCESS IS EXOTHERMIC.

Waste Disposal Methods:CURE, THEN BURY OR INCINERATE WHERE PERMITTED BY
FEDERAL, STATE AND LOCAL REGULATIONS. REMOVE SALVAGE VESSELS TO A
WASTE DISPOSAL SITE OPERATING IN COMPLIANCE WITH FEDERAL, STATE AND
LOCAL REGULATIONS .

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.